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U.S. Department of Energy
Office of Scientific and Technical Information

Coal/char reactivity

Technical Report ·
DOI:https://doi.org/10.2172/7129428· OSTI ID:7129428

The overall objective of the coal/char reactivity project is to expand the fundamental combustion data base to support existing and advanced atmospheric combustion systems. Investigations will focus primarily on elucidating the burning rates of chars under realistic flame conditions as a function of fuel and system parameters. Key issues include the relative contributions of inorganic constituents, and the surface and structural effects on the burning behavior of the low-rank coal-derived chars. A second objective is to perform fundamental investigations on the ignition mechanisms of single particles of low-rank coals by measuring rates of carbon monoxide and carbon dioxide production. This quarter's work included: design and testing of the videomicroscope sizing system; chars were prepared for combustion testing in the single-particle reactor using a flame burner. The following coals have been prepared: Beulah-Zap (PSOC- 1507), Lower Wilcox (PSOC-1443-D), New Mexico Blue (PSOC-1445-D), and Pittsburgh {number sign}8 (PSOC-1451-D); the morphologies of chars produced in the flame burner were examined; surface science studies using Auger and ESCA were performed on the suite of Beulah-Zap chars; the effect of various levels of sodium, potassium, and calcium on the burning rates of chars was examined; the ignition apparatus was completed and tested using Pittsburgh {number sign}8 (PSOC-1451) coal; the effect of moisture on the ignition and combustion of the vitrain lithotype of Beulah lignite (PSOC-1507) was determined; the combustion behaviors of vitrain, attritus, and fusain lithotypes of Beulah lignite were examined at 650{degree}C; the effect of temperature on the ignition and combustion of the vitrain lithotype of Beulah lignite and Pittsburgh {number sign}8 coal was examined; and the effect of coal rank on combustion behavior was determined at both 650{degree} and 1000{degree}C. 37 tabs., 29 figs., 21 tabs.

Research Organization:
North Dakota Univ., Grand Forks, ND (USA). Energy and Mineral Research Center
Sponsoring Organization:
DOE/FE
DOE Contract Number:
FC21-86MC10637
OSTI ID:
7129428
Report Number(s):
DOE/MC/10637-2827-Task-3.3; ON: DE90011400
Country of Publication:
United States
Language:
English