Reactivity of 4'-substituted 2,4-dinitrodiphenyl sulfides and sulfones during alkaline hydrolysis in aqueous dioxane

Journal Article · Thu Jan 09 23:00:00 EST 1986 · J. Gen. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:7129422

Ivanov, A V

This paper studies the kinetics of alkaline hydrolysis of 4'-substituted 2,4-dinitrodiphenyl sulfides (I), 2,4-dinitrodiphenyl sulfones (II), and 1-substituted 2,4-dinitrobenzenes (III) in a 40% dioxane-water solution. Analysis of the results obtained are presented and it is shown that in its character, the influence of the substituents in carrying out the alkaline hydrolysis reaction in 40% dioxane for the reaction series (I) obeys the general patterns of activated nucleophilic substitution, with the exception of 2,4-dinitro-4'-methylthiodiphenyl sulfide.

• Research Organization: L.N. Tolstoi State Pedagogic Institute
• OSTI ID: 7129422
• Journal Information: J. Gen. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Gen. Chem. USSR (Engl. Transl.); (United States) Vol. 55:7,PT.2; ISSN JGCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACTIVATION ENERGY
ALKALINE HYDROLYSIS
BINDING ENERGY
CHALCOGENIDES
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
DECOMPOSITION
DIOXANE
ELECTRON TRANSFER
ELECTRONIC STRUCTURE
ENERGY
HETEROCYCLIC COMPOUNDS
HYDROLYSIS
KINETICS
LYSIS
NITRO COMPOUNDS
NITROBENZENE
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
ORGANIC SULFUR COMPOUNDS
PHENOLATES
REACTION KINETICS
SOLVATION
SOLVOLYSIS
SULFIDES
SULFONES
SULFUR COMPOUNDS
VALENCE
YIELDS