Structural and stereochemical factors in the mass spectrometry of monocyclic hydrocarbons with geminal substituents

Journal Article · Fri Jan 10 04:00:00 EST 1986 · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)

OSTI ID:7129391

Golovkina, L S; Berman, S S; Petrov, A A; Rusinova, G V

This paper studies the mass spectra of geminally substituted monocyclic hydrocarbons of the composition C/sub 8/H/sub 16/-C/sub 11/H/sub 22/. An analogy in the principles of the decomposition of the molecular ions of geminally substituted cyclohexanes and cyclohexanes not having a geminal group in the molecule was established, as well as for the influence of stereochemical factors on the quantitative pattern of the mass spectra of the structural isomers. The comparative characteristics of the decomposition, under electron impact, of geminally substituted hydrocarbons of the cyclohexane and cyclopentane series were given. Diagnostic indexes for the identification of structural isomers were shown.

• Research Organization: Institute of Geology and Development of Combustible Minerals, Moscow
• OSTI ID: 7129391
• Journal Information: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 34:7,PT. 1; ISSN BACCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKANES
CHEMICAL REACTION KINETICS
COLLISIONS
CYCLOALKANES
CYCLOHEXANE
DISSOCIATION
DISSOCIATION ENERGY
ELECTRON COLLISIONS
ELECTRON-MOLECULE COLLISIONS
ENERGY
HYDROCARBONS
IONIZATION
ISOMERS
KINETICS
MASS SPECTRA
MOLECULAR STRUCTURE
MOLECULE COLLISIONS
ORGANIC COMPOUNDS
RADICALS
REACTION KINETICS
SPECTRA
STEREOCHEMISTRY
STRUCTURAL CHEMICAL ANALYSIS
VALENCE