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Simulated ground water leaching of in situ retorted or burned oil shale. [Effects of retorting time, temperature, and atmosphere on leaching properties of spent shales]

Conference · · Am. Chem. Soc., Div. Fuel Chem., Prepr.; (United States)
OSTI ID:7119705
With regard to a particular oil shale in-situ retorting site, the primary variables expected to influence the quantity of soluble salts available for possible groundwater leaching are retorting temperature, retorting time, and possible exposure to air to burn carbon from the shale. These variables were investigated for four temperatures, 430, 483, 630, and 780/sup 0/C, and two retorting times 15 and 30 hours. In general, 5 times less material was solubilized when oil shale was retorted in the absence of air than in the presence of air at the two lowest retorting temperatures. Retorting time was not a statistically important variable with regard to quantity of dissolved solids or pH of the leachate. As anticipated, increasing retorting temperatures resulted in increased amounts of leached solids and a higher pH leachate. Data are reported for leaching of many common elements from the oil shale--Li, Na, K, Mg, Ca, Sr, Zn, Cd, Hg, Cr, Fe, Mo, Al, and Pb.
Research Organization:
Texas Tech Univ., Lubbock
OSTI ID:
7119705
Conference Information:
Journal Name: Am. Chem. Soc., Div. Fuel Chem., Prepr.; (United States) Journal Volume: 21:6
Country of Publication:
United States
Language:
English