Metal formates via oxidation of metal carbonyl hydrides
Journal Article
·
· Organometallics; (United States)
- Univ. of Oklahoma, Norman, OK (United States)
The reaction of the metal carbonyl hydrides ([eta][sup 5]-C[sub 5]H[sub 4]CH[sub 3])[sub 2]M(CO)H M = Nb (1), Ta (2) with dioxygen produces the metal formato complexes ([eta][sup 5]-C[sub 5]H[sub 4]CH[sub 3])[sub 2]-Nb(O)([eta][sup 1]-O[sub 2]CH) (3) and ([eta][sup 5]-C[sub 5]H[sub 4]CH[sub 3])[sub 2]Ta(O)([eta][sup 1]-O[sub 2]CH) (4), apparently through the intermediacy of the corresponding CO[sub 2] complexes ([eta][sup 5]-C[sub 5]H[sub 4]CH[sub 3])[sub 2]M([eta][sup 2]-CO[sub 2])H. 23 refs.
- OSTI ID:
- 7114100
- Journal Information:
- Organometallics; (United States), Journal Name: Organometallics; (United States) Vol. 13:2; ISSN 0276-7333; ISSN ORGND7
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400102 -- Chemical & Spectral Procedures
400201* -- Chemical & Physicochemical Properties
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CARBOXYLIC ACID SALTS
CATALYSIS
CHALCOGENIDES
CHEMICAL REACTIONS
COMPLEXES
ELEMENTS
FORMATES
HYDRIDES
HYDROGEN COMPOUNDS
INFRARED SPECTRA
MAGNETIC RESONANCE
NIOBIUM COMPLEXES
NONMETALS
NUCLEAR MAGNETIC RESONANCE
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
OXIDATION
OXIDES
OXYGEN
OXYGEN COMPOUNDS
RESONANCE
SPECTRA
SYNTHESIS
TANTALUM COMPLEXES
TRANSITION ELEMENT COMPLEXES
400102 -- Chemical & Spectral Procedures
400201* -- Chemical & Physicochemical Properties
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CARBOXYLIC ACID SALTS
CATALYSIS
CHALCOGENIDES
CHEMICAL REACTIONS
COMPLEXES
ELEMENTS
FORMATES
HYDRIDES
HYDROGEN COMPOUNDS
INFRARED SPECTRA
MAGNETIC RESONANCE
NIOBIUM COMPLEXES
NONMETALS
NUCLEAR MAGNETIC RESONANCE
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
OXIDATION
OXIDES
OXYGEN
OXYGEN COMPOUNDS
RESONANCE
SPECTRA
SYNTHESIS
TANTALUM COMPLEXES
TRANSITION ELEMENT COMPLEXES