Structure of a new iodobismuthate: Tetra(n-butyl)ammonium 1,2; 1,2; 1,2; 2,3; 2,3; 2,3-hexa-. mu. -iodo-1,1,1,3,3,3-hexaiodotribismuthate(III) (3:1)
- Argonne National Lab., IL (United States)
(C{sub 16}H{sub 36}N){sub 3}Bi{sub 3}I{sub 12}, M{sub r}=2877{center dot}20, monoclinic, P2{sub 1}/c, a=17{center dot}796 (4), b=20{center dot}565 (6), c=23{center dot}414 (8){angstrom}, {beta} = 100{center dot}25 (2), V=8432 (4) {angstrom}{sup 3}, Z =4, D{sub x} = 2{center dot}266 Mg m{sup {minus}3}, {lambda}(Mo K{alpha}) = 0{center dot}71069 {angstrom}, {mu} = 10{center dot}61 mm{sup {minus}1}, F(000) = 5208, room temperature, final R = 0{center dot}140 for 4850 independent observed reflections with F{sub o}{gt}3{sigma}(F{sub o}). The compound contains a novel Bi{sub 3}I{sub 12}{sup 3{minus}} anion, consisting of three face-sharing (BiI{sub 6}) octahedra. The bridging Bi-I bond lengths average 3{center dot}078{angstrom} (inner Bi atom) and 3{center dot}330 {angstrom} (outer Bi atoms), whereas the bonds to terminal I atoms averaged 2{center dot}910 {angstrom}. Bond length constraints were applied to the refinement of the tetrabutylammonium cation C atoms.
- OSTI ID:
- 7109976
- Journal Information:
- Acta Crystallographica. Section C, Crystal Structure Communications; (Denmark), Journal Name: Acta Crystallographica. Section C, Crystal Structure Communications; (Denmark) Vol. C46; ISSN ACSCE; ISSN 0108-2701
- Country of Publication:
- United States
- Language:
- English
Similar Records
Crystal and molecular structures of the 4-(1H)-pyridone (=L) lanthanide complexes [l brace][GdL(NO[sub 3])[sub 3](H[sub 2]O)][center dot]CH[sub 3]OH[r brace][sub 2] and [DyL[sub 4](NO[sub 3])[sub 2]](NO[sub 3]) and of L[sub 2]HNO[sub 3]
Molecular and crystal structure of a [mu][sub 2]-[TCNE][sup 2[minus]] complex: [(Ph[sub 3]P)[sub 2](OC)Ir][sub 2][TCNE]
Related Subjects
400201* -- Chemical & Physicochemical Properties
AMINES
ANIONS
BISMUTH COMPOUNDS
BISMUTH IODIDES
CHARGED PARTICLES
COHERENT SCATTERING
CRYSTAL LATTICES
CRYSTAL STRUCTURE
DATA
DIFFRACTION
EXPERIMENTAL DATA
HALIDES
HALOGEN COMPOUNDS
INFORMATION
IODIDES
IODINE COMPOUNDS
IONS
LATTICE PARAMETERS
MONOCLINIC LATTICES
NUMERICAL DATA
ORGANIC COMPOUNDS
SCATTERING
X-RAY DIFFRACTION