Electrochemistry of molybdocene dichloride and tungstocene dichloride and the identification of metastable metallocenes

Journal Article · Thu Jan 09 23:00:00 EST 1986 · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)

OSTI ID:7109850

Strelets, V V; Kuzharenko, S V; Protskii, A N; Rusina, A; Soloveichuk, G L

This paper studies the possibilities of electrochemical generation and direct detection of Cp/sub 2/Mo and Cp/sub 2/W in the electroreduction of the corresponding complexes Cp/sub 2/MX/sub 2/ on a mercury electrode in THF or DMSO medium. In connection with the interest in cyclopentadienyl complexes of low-valence transition metals as possible catalysts of the electroreduction of CO, the authors studied the interaction of products of the electroreduction of Cp/sub 2/MoCl/sub 2/ and Cp/sub 2/WCl/sub 2/ with CO.

• Research Organization: Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka
• OSTI ID: 7109850
• Journal Information: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 34:7, PT.1; ISSN BACCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400400 -- Electrochemistry
500200* -- Environment
Atmospheric-- Chemicals Monitoring & Transport-- (-1989)
54 ENVIRONMENTAL SCIENCES
AIR POLLUTION ABATEMENT
ALKENES
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CATALYSTS
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL REACTIONS
CHEMISTRY
CHLORIDES
CHLORINE COMPOUNDS
COORDINATION VALENCES
CYCLOALKENES
CYCLOPENTADIENE
DIENES
DMSO
ELECTROCATALYSTS
ELECTROCHEMISTRY
ELECTROLYSIS
FURANS
HALIDES
HALOGEN COMPOUNDS
HETEROCYCLIC COMPOUNDS
HYDROCARBONS
LYSIS
MOLYBDENUM CHLORIDES
MOLYBDENUM COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
ORGANIC SULFUR COMPOUNDS
ORGANOMETALLIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
POLLUTION ABATEMENT
POLYENES
REDUCTION
REFRACTORY METAL COMPOUNDS
SULFOXIDES
TETRAHYDROFURAN
TRANSITION ELEMENT COMPOUNDS
TUNGSTEN CHLORIDES
TUNGSTEN COMPOUNDS
VALENCE