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Flowsheet for coprocessing uranium and plutonium

Technical Report ·
DOI:https://doi.org/10.2172/710122· OSTI ID:710122
A coprocessing solvent extraction flowsheet for recovering and purifying LWR fuels has been altered to achieve partial partioning of uranium and plutonium to eliminate streams with pure plutonium. Partial partitioning has been demonstrated in the laboratory with simulated feeds and irradiated LWR fuel solutions. Hydroxylamine nitrate was the reductant in these tests. Plutonium was concentrated by factors of 6 to 27.4. Tests have shown that 1 to 2 plutonium atoms are reduced for each hydroxylamine molecule consumed. Nitrite interferes with the reduction of plutonium, unless the hydroxylamine concentration is increased. 12 tables, 11 figures.
Research Organization:
Du Pont de Nemours (E.I.) and Co., Aiken, SC (United States). Savannah River Lab.
Sponsoring Organization:
USDOE
DOE Contract Number:
AC09-76SR00001
OSTI ID:
710122
Report Number(s):
DP--1505
Country of Publication:
United States
Language:
English

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