Rate constants for the reactions of hydrogen atoms with methylgermanes

Journal Article · Thu Aug 11 00:00:00 EDT 1977 · J. Phys. Chem.; (United States)

DOI:https://doi.org/10.1021/j100531a004· OSTI ID:7094787

Austin, E R; Lampe, F W

Absolute rate constants for the reaction of H atoms, formed by mercury photosensitization of H/sub 2/-substrate mixtures at 32/sup 0/C, with (CH/sub 3/)/sub n/GeH/sub 4-n/ for n = 1, 2, 3 have been determined in experiments involving the competitive reaction of H atoms with Si/sub 2/H/sub 6/. Arrhenius parameters and bond dissociation energies have been estimated for this series of methylgermanes.

• Research Organization: Pennsylvania State Univ., University Park
• OSTI ID: 7094787
• Journal Information: J. Phys. Chem.; (United States), Journal Name: J. Phys. Chem.; (United States) Journal Issue: 16 Vol. 81:16; ISSN JPCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
400301 -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
CRYOGENIC FLUIDS
ELEMENTS
FLUIDS
GERMANES
GERMANIUM COMPOUNDS
HYDROGEN
KINETICS
NONMETALS
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
REACTION KINETICS