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Study of the saturated and unsaturated oils from shale

Journal Article · · Chem. Metall. Eng.; (United States)
OSTI ID:7092979
Shale oils prepared from oil shales of Quebec, England, Scotland, Colorado, Wyoming, Utah, and Nevada were studied to determine the extent and cause of unsaturation, distribution of saturates, effect of cracking on unsaturation, and some of the properties of the unsaturated products. Colorado shale oil contained 11.6 to 28.0 percent saturates. None of the retorting conditions used produced more than 30 percent saturates, and the smallest amount was produced when steam retorting was used to minimize cracking. Insufficient organic hydrogen is present in kerogen to produce saturated compounds with all of the carbon; consequently, for maximum yield the oil must be highly unsaturated. Decomposition occurred during redistillation of the shale oil and was accompanied by a considerable increase in the saturation of the oil.
OSTI ID:
7092979
Journal Information:
Chem. Metall. Eng.; (United States), Journal Name: Chem. Metall. Eng.; (United States) Vol. 24; ISSN CMENA
Country of Publication:
United States
Language:
English