Evaluation of intermolecular attractive forces in coal derived liquids. Quarterly report, February 1984-April 1984

Technical Report · Fri Jun 01 04:00:00 EDT 1984

OSTI ID:7089878

Jones, M B

Quantitative solubility measurements of nine model compounds and seven coal derived preasphaltene samples (four native, three derivatized by acetylation) have been carried out in twelve solvents. Plots of model compound solubility versus solubility parameter exhibited, in general, maxima of ca. 9 to 9.5 H, in agreement with literature results for coal derived asphaltenes. Similar plots for the native preasphaltene samples revealed maxima of ca. 10.5 to 11 H, in accord with reported studies. Little correlation between solubility of model compounds and either net hydrogen bonding indices or donor number minus acceptor number values of solvents was observed. General trends of increasing dissolvability of preasphaltenes with increasing net hydrogen bonding indices or increasing donor number minus acceptor number values of solvents were noted. 13 figures, 5 tables.

• Research Organization: North Dakota Univ., Grand Forks (USA)
• DOE Contract Number: FG22-83PC60808
• OSTI ID: 7089878
• Report Number(s): DOE/PC/60808-2; ON: DE84013317
• Country of Publication: United States
• Language: English

Related Subjects

01 COAL, LIGNITE, AND PEAT
010405* -- Coal
Lignite
& Peat-- Hydrogenation & Liquefaction
ACETONE
ACETYLATION
ACYLATION
ALCOHOLS
ALKANES
ALKYLATED AROMATICS
AROMATICS
AZINES
CHEMICAL REACTIONS
COAL LIQUEFACTION
COAL LIQUIDS
CYCLOHEXANONE
DERIVATIZATION
DMSO
ETHERS
ETHYL ETHER
FLUIDS
FURANS
HETEROCYCLIC COMPOUNDS
HEXANE
HYDROCARBONS
HYDROXY COMPOUNDS
KETONES
LIQUEFACTION
LIQUIDS
METHANOL
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
ORGANIC SOLVENTS
ORGANIC SULFUR COMPOUNDS
PYRIDINE
PYRIDINES
SOLUBILITY
SOLVENT PROPERTIES
SOLVENTS
STRUCTURAL MODELS
SULFOXIDES
TETRAHYDROFURAN
THERMOCHEMICAL PROCESSES
TOLUENE