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Raman intensities of overtones and combination bands of C/sub 2/H/sub 2/, C/sub 2/HD, and C/sub 2/D/sub 2/

Journal Article · · J. Chem. Phys.; (United States)
OSTI ID:7083352
Measurements of absolute gas phase vibrational Raman scattering cross sections of binary overtone and combination bands of C/sub 2/H/sub 2/,C/sub 2/HD, and C/sub 2/D/sub 2/ are reported. Calculated values for these cross sections, which take into account the contribution of the anharmonic force field and the electro-optical anharmonicity, are also presented. Within limitations due to approximations in the theory and uncertainties in the parameters, the comparison between the experimental cross sections and the calculated ones is quite encouraging.
Research Organization:
Instituto de Estructura de la Materia, C.S.I.C. Serrano, 119, Madrid (6), Spain
OSTI ID:
7083352
Journal Information:
J. Chem. Phys.; (United States), Journal Name: J. Chem. Phys.; (United States) Vol. 77:9; ISSN JCPSA
Country of Publication:
United States
Language:
English