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Ozone transport from stratosphere to troposphere

Journal Article · · Geophys. Res. Lett.; (United States)
/sup 7/Be produced by the interaction of cosmic rays with oxygen and nitrogen, predominantly in the stratosphere, has been used to identify and measure stratospheric ozone at the ground level. Simultaneous measurements at Whiteface Mountain, New York, in July 1975 show that the maximum /sup 7/Be concentrations are accompanied by increased ozone concentrations. Peaks in /sup 7/Be concentrations occurred on July 5-6, 11-12, 16-17, 23, and 27. Ozone peaks were observed on July 7-9, 11, 18, 24, and 27. Isentropic trajectory calculations also showed that the trajectories reaching Whiteface Mountain on July 11-12, 15-16, 23, and 27 had stratospheric origin. One-day delay in ozone peaks on July 7-9, 18, and 24 is attributed to increased tropospheric ozone production. The observed relationship between /sup 7/Be and ozone is used to deduce an upper limit of 37 ppb stratospheric ozone at Whiteface Mountain during July 1975. Thus, even during midsummer months, when stratospheric-tropospheric mass exchange is not at a maximum, stratospheric ozone may contribute substantially to the national ambient air quality standard of 80 ppb.
Research Organization:
Division of Laboratories and Research, New York State Department of Health, Albany, N.Y. 12201
OSTI ID:
7082756
Journal Information:
Geophys. Res. Lett.; (United States), Journal Name: Geophys. Res. Lett.; (United States) Vol. 4:9; ISSN GPRLA
Country of Publication:
United States
Language:
English