High-pressure vapor-liquid equillibrium data of the 10-component system hydrogen, carbon monoxide, carbon dioxide, water, methane, ethane, propane, methanol, ethanol, and 1-propanol at 313. 4 and 333. 4 K

Journal Article · Mon Jan 01 04:00:00 EST 1990 · Journal of Chemical and Engineering Data; (USA)

DOI:https://doi.org/10.1021/je00059a021· OSTI ID:7080006

Suzuki, K; Sue, H ^[1]; Itou, M; Smith, R L; Inomata, H; Arai, K; Saito, S ^[2]

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1. Central Research Lab., Idemitsu Kosan Co., Ltd., Sodegaura, Chiba (JP)
2. Tohoku Univ., Sendai (Japan)

Production of C{sub 1} to C{sub 6} alcohols from syngas is one of the most promising developments in C{sub 1} chemistry. The reaction mechanism, which obeys a Schultz--Flory polymerization law, leads to simultaneous production of alcohols and hydrocarbons. The rate of heavier alcohols and hydrocarbons decreases with their increasing carbon number. A water-gas shift reaction occurs as a side reaction. Therefore, it is necessary to know the vapor-liquid equilibria of the H{sub 2}, CO, CO{sub 2}, CH{sub 4}, C{sub 2}H{sub 6}, C{sub 3}H{sub 8}, H{sub 2}O, CH{sub 3}OH, C{sub 2}H{sub 5}OH, and {ital n}-C{sub 3}H{sub 7}OH system for separation process design. In a previous publication, the authors reported vapor-liquid equilibrium data on CO{sub 2}-alcohols, CH{sub 4}-alcohols, and C{sub 2}H{sub 6}-alcohols. In this work the authors report isothermal high-pressure vapor-liquid equilibrium data for the H{sub 2}, CO, CO{sub 2}, CH{sub 4}, C{sub 2}H{sub 6}, C{sub 3}H{sub 8}, H{sub 2}O, CH{sub 3}OH, C{sub 2}H{sub 5}OH, and {ital n}-C{sub 3}H{sub 7}OH system in the 313--333 K temperature range.

• OSTI ID: 7080006
• Journal Information: Journal of Chemical and Engineering Data; (USA), Journal Name: Journal of Chemical and Engineering Data; (USA) Vol. 35:1; ISSN 0021-9568; ISSN JCEAA
• Country of Publication: United States
• Language: English

Related Subjects

09 BIOMASS FUELS
091000* -- Biomass Fuels-- Properties & Composition-- (1990-)
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400105 -- Separation Procedures
ALCOHOLS
ALKANES
CARBON COMPOUNDS
CARBON DIOXIDE
CARBON MONOXIDE
CARBON OXIDES
CHALCOGENIDES
CHEMICAL REACTION KINETICS
DISPERSIONS
ELEMENTS
EQUILIBRIUM
ETHANE
ETHANOL
FLUIDS
GASES
HIGH PRESSURE
HYDROCARBONS
HYDROGEN
HYDROXY COMPOUNDS
KINETICS
LIQUIDS
METHANE
METHANOL
MIXTURES
NONMETALS
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PROPANE
PROPANOLS
REACTION KINETICS
SEPARATION PROCESSES
VAPORS