Silylene- and disilyleneacetylene polymers from trichloroethylene
Patent
·
OSTI ID:7072324
Organosilane polymers having recurring silyleneacetylene and/or disilyleneacetylene units are prepared in a one-pot synthesis from trichloroethylene. Depending on the organic substituents (R and R[prime]), these polymers have useful film-forming properties, and are converted to the ceramic, silicon carbide upon heating in very uniform high yields. They can also be pulled into fibers.
- DOE Contract Number:
- W-7405-ENG-82
- Assignee:
- Iowa State Univ. Research Foundation, Inc., Ames, IA (United States)
- Patent Number(s):
- US 4940767; A
- Application Number:
- PPN: US 7-226444
- OSTI ID:
- 7072324
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
36 MATERIALS SCIENCE
360201* -- Ceramics
Cermets
& Refractories-- Preparation & Fabrication
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201 -- Chemical & Physicochemical Properties
CARBIDES
CARBON COMPOUNDS
CHEMICAL PREPARATION
CHLORINATED ALIPHATIC HYDROCARBONS
EXTRUSION
FABRICATION
HALOGENATED ALIPHATIC HYDROCARBONS
MATERIALS WORKING
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC POLYMERS
ORGANIC SILICON COMPOUNDS
POLYMERS
PRECURSOR
SILICON CARBIDES
SILICON COMPOUNDS
SYNTHESIS
360201* -- Ceramics
Cermets
& Refractories-- Preparation & Fabrication
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201 -- Chemical & Physicochemical Properties
CARBIDES
CARBON COMPOUNDS
CHEMICAL PREPARATION
CHLORINATED ALIPHATIC HYDROCARBONS
EXTRUSION
FABRICATION
HALOGENATED ALIPHATIC HYDROCARBONS
MATERIALS WORKING
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC POLYMERS
ORGANIC SILICON COMPOUNDS
POLYMERS
PRECURSOR
SILICON CARBIDES
SILICON COMPOUNDS
SYNTHESIS