Characterization of the isolated Y C[sub 82]

Journal Article · Wed Oct 05 00:00:00 EDT 1994 · Journal of the American Chemical Society; (United States)

DOI:https://doi.org/10.1021/ja00099a079· OSTI ID:7070443

Kikuchi, Koichi; Nakao, Yasuhiko; Suzuki, Sinzo; Achiba, Yohji ^[1]; Suzuki, Toshiyasu; Maruyama, Yusei ^[2]

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1. Tokyo Metropolitan Univ. (Japan)
2. Institute for Molecular Science, Okazaki (Japan)

We report here the first isolation and characterization of Y C[sub 82] in comparison with La C[sub 82]. The electronic structure of the major Y C[sub 82] isomer, examined by the electronic absorption spectra and the electrochemistry, is almost identical to that of the major La C[sub 82] isomer, although the ionization potentials and ionic radii of the metals are different. This indicates that Y C[sub 82]-A would have a cage structure and an oxidation state of the metal similar to those of La Cr[sub 82]-A. 15 refs., 3 figs., 1 tab.

• OSTI ID: 7070443
• Journal Information: Journal of the American Chemical Society; (United States), Journal Name: Journal of the American Chemical Society; (United States) Vol. 116:20; ISSN JACSAT; ISSN 0002-7863
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
661300 -- Other Aspects of Physical Science-- (1992-)
71 CLASSICAL AND QUANTUM MECHANICS
GENERAL PHYSICS
ABSORPTION SPECTRA
CARBON
CHEMISTRY
ELECTROCHEMISTRY
ELECTRON SPECTRA
ELECTRONIC STRUCTURE
ELEMENTS
FULLERENES
IONIZATION POTENTIAL
LANTHANUM COMPOUNDS
NONMETALS
RARE EARTH COMPOUNDS
SOOT
SPECTRA
TRANSITION ELEMENT COMPOUNDS
VALENCE
YTTRIUM COMPOUNDS