Synthesis of substituted 1-methally1 derivatives of o- and m-carboranes and some of their transformations

Journal Article · Fri Jan 31 23:00:00 EST 1986 · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)

OSTI ID:7066294

Kovredov, A I; Shemyakin, N F; Zakharkin, L I

This paper presents the synthesis of 1-methally1 derivatives of o- and m-carbonanes and studies the alkylation of benzene using these compounds. The synthesis was carried out using 1-lithium-substituted o-carboranes and methyllyl chloride in ether-benzene. The reaction of lithium derivatives of 0- or m-carboranes with methylly1 chloride in ether-benzene gave 1-methy1-2-methally1-o-carborane, 1-pheny1-2-methally1-o-carborane, 1,2-dimethally1-o-carborane, and 1,7-dimethally1-m-carborane.

• Research Organization: A.N. Nesmeyanov Institute of Heteroorganic Compounds, Moscow
• OSTI ID: 7066294
• Journal Information: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 34:8,PT.2; ISSN BACCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALCOHOLS
ALKALI METALS
ALKANES
ALKYL RADICALS
ALKYLATION
AROMATICS
BENZENE
BORON COMPOUNDS
CARBON COMPOUNDS
CARBORANES
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
COMPLEXES
ELEMENTS
HEPTANE
HYDROCARBONS
HYDROXY COMPOUNDS
KINETICS
LITHIUM
LITHIUM COMPLEXES
METALS
METHYL RADICALS
ORGANIC COMPOUNDS
RADICALS
REACTION KINETICS
SYNTHESIS
YIELDS