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1st-Principles Step- and Kink-Formation Energies on Cu(111)

Journal Article · · Physical Reivew B

In rough agreement with experimental values derived from Cu island shapes vs. temperature, ab-initio calculations yield formation energies of 0.27 and 0.26 eV/ step-edge-atom for (100)- and (111)-micro facet steps on Cu(lll), and 0.09 and 0.12 eV per kink in those steps. Comparison to ab-initio results for Al and Pt shows that as a rule, the average formation energy of straight steps on a close-packed metal surface equals -7% of the metal's cohesive energy.

Research Organization:
Sandia National Laboratories (SNL), Albuquerque, NM, and Livermore, CA
Sponsoring Organization:
USDOE
DOE Contract Number:
AC04-94AL85000
OSTI ID:
7065
Report Number(s):
SAND99-1327J; ON: DE00007065
Journal Information:
Physical Reivew B, Journal Name: Physical Reivew B
Country of Publication:
United States
Language:
English

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