Reaction of divinyl sulfoxide with 2H,6H-2,6-dimethyl-4-amino-1,3,5dithiazine

Journal Article · Tue Oct 01 00:00:00 EDT 1985 · J. Appl. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:7058320

Amosova, S V; Gavrilova, G M; Gostevskaya, V I; Gusarova, N K

It has been shown that 4-butyl-4-octadecyl-1,4-tetrahydrothiazinium-1-oxide bromide, synthesized from divinyl sulfoxide, is an effective flotation reagent and can be used as a collector in purification of wastewaters. With the aim of synthesizing new potential surfactants containing several reactive centers, the authors studied the reaction of divinyl sulfoxide with 2H,6H-2,6-dimethyl-4-amino-1,3,5-dithiazine (I), a product of heterocyclization of divinyl sulfide with thiourea. In that reaction, polyaddition leading to oligomeric products is accompanied by destruction of the heterocyclic compound.

• Research Organization: Irkutsk Institute of Organic Chemistry, Siberian Branch Acad. of Sci
• OSTI ID: 7058320
• Journal Information: J. Appl. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Appl. Chem. USSR (Engl. Transl.); (United States) Vol. 58:4,PT.2; ISSN JAPUA
• Country of Publication: United States
• Language: English

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54 ENVIRONMENTAL SCIENCES
ABSORPTION SPECTRA
ALCOHOLS
AZINES
CARBONIC ACID DERIVATIVES
CHEMICAL ANALYSIS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
DIAGRAMS
DMSO
ETHANOL
HETEROCYCLIC COMPOUNDS
HYDROGEN COMPOUNDS
HYDROXY COMPOUNDS
KINETICS
LIQUID WASTES
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC SULFUR COMPOUNDS
OXYGEN COMPOUNDS
POLLUTION ABATEMENT
PURIFICATION
QUANTITATIVE CHEMICAL ANALYSIS
QUANTITY RATIO
REACTION KINETICS
SPECTRA
SULFOXIDES
SURFACTANTS
SYNTHESIS
THIOUREAS
WASTE WATER
WASTES
WATER
WATER POLLUTION ABATEMENT
YIELDS