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New values for some /sup 4/He I 1snl energy levels, ionization energies, and Lamb shifts

Journal Article · · Phys. Rev. A; (United States)
Recent experimental determinations of energy separations within the 1snl term system (n = 2--6) have been used to reevaluate 35 levels. Most of the levels have estimated errors less than 0.001 cm/sup -1/ relative to the 2 /sup 3/P levels. Addition of accurate theoretical term values (ionization energies) available for several 1snl levels to the corresponding experimental level values gives generally consistent values for the principal ionization energy (E/sub I/). The theoretical energies are further confirmed by the agreement of the weighted average of seven of these E/sub I/ values with a value obtained by fitting Ritz formulas to three accurately determined 1snl series; the suggested new E/sub I/ is 198 310.7745(40) cm/sup -1/ on an energy scale fixed by the value 171 135.0000 cm/sup -1/ for 2 /sup 1/P. Lamb shifts are derived for the 2, 3, 4 /sup 3/S/sub 1/, 2 /sup 1/S/sub 0/, 2 /sup 3/P/sub 1/, and 2/sup 1/P/sub 1/ levels as differences between experimental term values obtained with the new E/sub I/ and corresponding calculated term values not including Lamb shifts. The experimental and calculated values for the 1s/sup 2/ /sup 1/S/sub 0/ ground level relative to the present 1snl excited-level system are 0.00 +- 0.15 and 0.073 +- 0.009 cm/sup -1/, respectively, so that a approx.20-fold increase in the experimental accuracy would be required to test the calculated ground-level Lamb shift.
Research Organization:
National Measurement Laboratory, National Bureau of Standards, Washington, DC 20234
OSTI ID:
7051370
Journal Information:
Phys. Rev. A; (United States), Journal Name: Phys. Rev. A; (United States) Vol. 29:4; ISSN PLRAA
Country of Publication:
United States
Language:
English