Reports of investigations on: Derivation of an infinite-dilution activity coefficient model and application to two-component vapor/liquid equilibria data: Final report

Technical Report · Mon Feb 01 00:00:00 EST 1988

OSTI ID:7042713

Roper, V P; Kobayashi, R

Infinite-dilution fugacity coefficients were obtained for the system fluorene/phenanthrene at thirteen temperatures by fitting total pressure across the entire mole fraction range by a computer routine. A thermodynamically consistent routine, that allowed for both positive and negative pressure deviations from the ideal values, was used to correlate data over the full mole fraction range from 0 to 1. The four-suffix Margules activity coefficient model without modification essentially served this purpose since total pressures and total pressure derivatives with respect to mole fraction were negligible compared to pressure measurement precision. The water/ethanol system and binary systems comprised of aniline, chlorobenzene, acetonitrile and other polar compounds were fit for total pressure across the entire mole fraction range for binary Vapor-Liquid-Equilbria (VLE) using the rigorous, thermodynamically consistent Gibbs-Duhem Relation derived by Ibl and Dodge. Data correlation was performed using a computer least squares procedure. Infinite-dilution fugacity coefficients were obtained using a modified Margules activity coefficient model.

• Research Organization: Rice Univ., Houston, TX (USA). Dept. of Chemical Engineering
• DOE Contract Number: FG22-83PC60037
• OSTI ID: 7042713
• Report Number(s): DOE/PC/60037-T8; ON: DE88007517
• Country of Publication: United States
• Language: English

Related Subjects

01 COAL, LIGNITE, AND PEAT
BINARY-FLUID SYSTEMS
VAPOR PRESSURE
COAL LIQUIDS
POLAR COMPOUNDS
THERMODYNAMIC PROPERTIES
VAPORS
ACETONITRILE
BINARY MIXTURES
BOILING POINTS
CORRELATIONS
DILUTION
ETHANOL
FLUORENE
LIQUIDS
MATHEMATICAL MODELS
PHENANTHRENE
PROGRESS REPORT
TEMPERATURE DEPENDENCE
TEMPERATURE EFFECTS
THERMODYNAMICS
WATER
ALCOHOLS
AROMATICS
CONDENSED AROMATICS
DISPERSIONS
DOCUMENT TYPES
ENERGY SYSTEMS
FLUIDS
GASES
HYDROCARBONS
HYDROGEN COMPOUNDS
HYDROXY COMPOUNDS
MIXTURES
NITRILES
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXYGEN COMPOUNDS
PHYSICAL PROPERTIES
TRANSITION TEMPERATURE
010600* - Coal
Lignite
& Peat- Properties & Composition
010405 - Coal
Lignite
& Peat- Hydrogenation & Liquefaction