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Title: Optical and mechanical properties of optically transparent poly(methyl methacrylate) composites at elevated temperatures

Miscellaneous ·
OSTI ID:7039376

Highly transparent poly(methyl methacrylate) (PMMA) composites were made by carefully matching the refractive index of the glass fiber reinforcement with the PMMA matrix using a hot pressing method. Composites containing 10.4 vol% unidirectional glass fiber and 0.68 mm in thickness had an optical transmission of 92% in the visible region. The room temperature tensile strength of the composites in the direction of the fiber was twice that of pure PMMA and the strength-to-weight ratio was increased about 1.7 times. The decrease in tensile strength with temperature for the composite followed the rule of mixtures. The transparency of the composites is temperature dependent because of the different temperature coefficient of refractive index for the glass fiber and PMMA. Thermal aging at temperatures near T{sub g} of the PMMA matrix caused dimensional changes and a reduction in optical transmission and clarity. The temperature where aging commences can be shifted from 100 to 115 C by eliminating low T{sub g} material(s) in the composite by hot pressing at higher temperature.

Research Organization:
Missouri Univ., Rolla, MO (United States)
OSTI ID:
7039376
Resource Relation:
Other Information: Thesis (Ph.D.)
Country of Publication:
United States
Language:
English