Synthesis and characterization of perovskite-type BaTl sub 0. 5 Sb sub 0. 5 O sub 3 and BaTl sub 0. 5+x Sb sub 0. 5 minus x ( sub 3 minus x )

Journal Article · Sat Nov 30 23:00:00 EST 1991 · Journal of Solid State Chemistry; (United States)

DOI:https://doi.org/10.1016/0022-4596(91)90128-5· OSTI ID:7038952

Subramanian, M A; Ganguli, A K ^[1]; Willmer, K L; Greedan, J E ^[2]

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1. Dupont Co., Deepwater, NJ (United States)
2. McMaster Univ., Hamilton, Ontario (Canada)

BaTl{sub 0.5}Sb{sub 0.5}O{sub 3} has been synthesized for the first time and has a perovskite-related structure. Neutron diffraction studies show that this compound is isostructural to BaPbO{sub 3}. Solid solutions of the type BaTl{sub 0.5+x}Sb{sub 0.5{minus}x}O{sub 3{minus}x} are also prepared for x values up to 0.5; electrical measurements showed that all the compounds are semiconducting.

• OSTI ID: 7038952
• Journal Information: Journal of Solid State Chemistry; (United States), Journal Name: Journal of Solid State Chemistry; (United States) Vol. 95:2; ISSN 0022-4596; ISSN JSSCB
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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ALKALINE EARTH METAL COMPOUNDS
ANTIMONY COMPOUNDS
ANTIMONY OXIDES
BARIUM COMPOUNDS
BARIUM OXIDES
CHALCOGENIDES
CHEMICAL PREPARATION
COHERENT SCATTERING
CRYSTAL STRUCTURE
DATA
DIFFRACTION
DISPERSIONS
ELECTRIC CONDUCTIVITY
ELECTRICAL PROPERTIES
EXPERIMENTAL DATA
INFORMATION
MATERIALS
MIXTURES
NEUTRON DIFFRACTION
NUMERICAL DATA
OXIDES
OXYGEN COMPOUNDS
PHYSICAL PROPERTIES
RARE EARTH COMPOUNDS
SCATTERING
SEMICONDUCTOR MATERIALS
SOLID SOLUTIONS
SOLUTIONS
STOICHIOMETRY
SYNTHESIS
THULIUM COMPOUNDS
THULIUM OXIDES
X-RAY DIFFRACTION