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Universal aspects of the atomic-scale friction of diamond surfaces

Journal Article · · Journal of Physical Chemistry
;  [1]
  1. Naval Academy, Annapolis, MD (United States)

Several facets are observed when diamond films are produced by chemical vapor deposition methods. It is unknown, however, if all of these facets exhibit the same atomic-scale frictional behavior. In an effort to determine whether a facet or surface topological dependence of the atomic-scale friction of diamond exists, we have used molecular dynamics simulations to examine the friction which occurs when the (100)-(2 x 1) reconstructed surfaces of two diamond lattices are placed in sliding contact. Calculations are performed as a function of applied load, crystallographic sliding direction, and sliding velocity. Results from these calculations are compared with previous computations performed on a diamond (111) surface. We find that the general dependence of the friction coefficint, {mu}, on the applied load is similar, regardless of the facet. Indeed, this conclusion is supported by atomic force microscope experiments which have examined the friction of diamond (100) and (111) surfaces. While the friction coefficients, and therefore the amount of energy dissipation, are similar regardless of facet, the atomic-scale motions which lead to energy dissipation differ slightly depending on the facet. 47 refs., 9 figs.

Sponsoring Organization:
USDOE
OSTI ID:
70368
Journal Information:
Journal of Physical Chemistry, Journal Name: Journal of Physical Chemistry Journal Issue: 24 Vol. 99; ISSN JPCHAX; ISSN 0022-3654
Country of Publication:
United States
Language:
English

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