Novel Dodecaarylporphyrins: Synthesis and Variable Temperature NMR Studies
Journal Article
·
· Tetrahedron Letter
OSTI ID:7036
- Sandia National Laboratories
An investigation of the synthesis of novel dodecaarylporphyrins using the Suzuki coupling reaction of arylboronic acids with octabromotetraarylporphyrins is reported. Studies of the dynamic properties of these new porphyrins using variable temperature (VT) 1H NMR spectroscopy and molecular mechanics provide interesting insights into their dynamic properties, including the first determination of {beta} aryl rotation in a porphyrin system.
- Research Organization:
- Sandia National Laboratories (SNL), Albuquerque, NM, and Livermore, CA
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC04-94AL85000
- OSTI ID:
- 7036
- Report Number(s):
- SAND99-1125J; ON: DE00007036
- Journal Information:
- Tetrahedron Letter, Journal Name: Tetrahedron Letter
- Country of Publication:
- United States
- Language:
- English
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