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Hierarchical structure in the 3[nu][sub 1] band of propyne

Journal Article · · Journal of Chemical Physics; (United States)
DOI:https://doi.org/10.1063/1.467639· OSTI ID:7032795
;  [1];  [2]
  1. Chemistry Division, Argonne National Laboratory, Argonne, Illinois 60439 (United States)
  2. Department of Chemistry, Princeton University, Princeton, New Jersey 08542 (United States)
A hierarchical analysis of the 3[nu][sub 2] band of propyne shows that there are distinct tiers of states and demonstrates that the major avenue for vibrational mixing is anharmonic coupling for [ital K][prime]=0 up to a time of approximately one ns.
Research Organization:
Argonne National Laboratory (ANL), Argonne, IL
DOE Contract Number:
W-31109-ENG-38
OSTI ID:
7032795
Journal Information:
Journal of Chemical Physics; (United States), Journal Name: Journal of Chemical Physics; (United States) Vol. 101:3; ISSN JCPSA6; ISSN 0021-9606
Country of Publication:
United States
Language:
English