NMR study of the solution-state dynamics and solid-state structure of tri-n-butyltin fluoride

Journal Article · Thu May 05 04:00:00 EDT 1994 · Journal of Physical Chemistry; (United States)

DOI:https://doi.org/10.1021/j100069a025· OSTI ID:7019553

Kim, Y W; Labouriau, A; Taylor, C M; Earl, W L; Werbelow, L G ^[1]

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1. Los Alamos National Lab., NM (United States)

Dynamics and structure of tri-n-butyltin fluoride in n-hexane solutions were probed using (tin-119) nuclear magnetic resonance spin relaxation methodologies. Significant relaxation-induced polarization transfer effects were observed and exploited. The experimental observations indicate that the tri-n-butyl fluoride exists in a polymeric form in solution. For a 0.10% (w/w) solution at 25 [degree]C, NMR reveals significant orientational/exchange relaxation on both the microsecond and nanosecond time scales. Solution-state and solid-state parameters are compared and contrasted. 26 refs., 3 figs., 1 tab.

• OSTI ID: 7019553
• Journal Information: Journal of Physical Chemistry; (United States), Journal Name: Journal of Physical Chemistry; (United States) Vol. 98:18; ISSN JPCHAX; ISSN 0022-3654
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400102 -- Chemical & Spectral Procedures
400201* -- Chemical & Physicochemical Properties
99 GENERAL AND MISCELLANEOUS
990200 -- Mathematics & Computers
ALKANES
COMPUTERIZED SIMULATION
DAYS LIVING RADIOISOTOPES
DISPERSIONS
EVEN-ODD NUCLEI
FLUORINE COMPOUNDS
HALOGEN COMPOUNDS
HEXANE
HYDROCARBONS
INTERMEDIATE MASS NUCLEI
INTERNAL CONVERSION RADIOISOTOPES
ISOMERIC TRANSITION ISOTOPES
ISOTOPES
MAGNETIC RESONANCE
MATHEMATICAL MODELS
MIXTURES
NUCLEAR MAGNETIC RESONANCE
NUCLEI
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
POLYMERS
RADIOISOTOPES
RESONANCE
SIMULATION
SOLUTIONS
STABLE ISOTOPES
TIN 119
TIN COMPOUNDS
TIN ISOTOPES