Polyaniline: Factors affecting conductivity and mechanical properties
The main objectives of this study were: (a) to study electronic and mechanical properties of films of the conducting polymer, polyaniline, in the doped and undoped emeraldine oxidation state, (b) to study how the electronic and mechanical properties were modified through mechanical stretch-orientation of the films, (c) to study the effect of water vapor on the conductivity of stretched protonic acid doped films, (d) to observe changes in tensile strength and Young's modulus when selected plasticizers were introduced into the films, (e) to observe, using UV/Vis spectroscopy, the effect that neutral salts in the doping media have on the doping level of thin, optically transparent films of polyaniline, (f) to use thin, optically transparent films to spectroscopically study (by UV/Vis) hysteresis in the doping and undoping behavior of polyaniline. The significant results and conclusions are: (a) mechanical stretch-orientation of polyaniline increased the tensile strength of emeraldine base films, (b) the conductivity of doped films of polyaniline was increased approximately two orders of magnitude by stretch-orientation (four-fold elongation) from [approximately]5 S/cm to [approximately]90 S/cm, (c) an increase in the relative percent crystallinity (by x-ray diffraction) upon stretch-orientation of emeraldine base films, (d) the removal of water vapor was found to decrease the conductivity of stretched emeraldine, (e) both tensile strength and Young's modulus are decreased by the introduction of plasticizers and [open quotes]dopant plasticizers[close quotes] into the films, (f) no loss in conductivity was observed due to the addition of plasticizers, (g) the presence of neutral salts in the doping media increased the doping level of thin films of polyaniline, (h) observed hysteresis upon doping and undoping thin polyaniline films is due to irreversible morphological changes that take place in polyaniline upon doping and undoping.
- Research Organization:
- Pennsylvania Univ., Philadelphia, PA (United States)
- OSTI ID:
- 7016879
- Resource Relation:
- Other Information: Thesis (Ph.D.)
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
74 ATOMIC AND MOLECULAR PHYSICS
ANILINE
CRYSTAL DOPING
ELECTRIC CONDUCTIVITY
MECHANICAL PROPERTIES
ELECTRONIC STRUCTURE
ORGANIC POLYMERS
TENSILE PROPERTIES
VALENCE
YOUNG MODULUS
AMINES
AROMATICS
ELECTRICAL PROPERTIES
ORGANIC COMPOUNDS
PHYSICAL PROPERTIES
POLYMERS
360606* - Other Materials- Physical Properties- (1992-)
360603 - Materials- Properties
664000 - Atomic & Molecular Physics- (1992-)