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Single-Sinter Process for Manufacturing UO2-Zro2 and UO2-ThO2, Fuel Pllets-A Feasibility Study

Technical Report ·
OSTI ID:7013812
A single-sinter process would offer a major cost savings over the conventional double-sinter process for the production of binary oxide nuclear fuel pellets. In the former case, only the pellet is sintered, while in the latter case, both powder (for homogeneity) and pellet are sintered. Four methods were attempted on 32 to 36 wt % UO/sub 2/-ZrO/sub 2/ compositions: separate ball milling of the two powders and subsequent blending, simultaneous ball milling, simultaneous planetary milling, and simultaneous colloid milling. Simultaneous planetary milling was also tried on an 8 wt % UO/sub 2/-ThO/sub 2/ composition. The ball milling methods were completely unsatisfactory in achieving density and U homogeneity. The planetary-milled pellets achieved density but not homogeneity. Colloid-milled pellets achieved density and fair homogeneity. Homogeneity was determined by electron microprobe and metallography techniques. No satisfactory pellets were fabricated with 8 wt % UO/sub 2/-ThO/sub 2/ composition by planetary milling both powders together. There are indications that the objective could be achieved with modification of the efforts described. (NSA 21: 11281)
Research Organization:
Bettis Atomic Power Lab., Pittsburgh, PA (USA)
DOE Contract Number:
AT(11-1)-GEN-14
OSTI ID:
7013812
Report Number(s):
WAPD-TM-607
Country of Publication:
United States
Language:
English