New catalysts for the indirect liquefaction of coal. Second annual technical report, August 1, 1981-July 31, 1982
Series of zeolite-supported iron-containing catalysts with weight percent iron (% Fe) varying from approx. 1 to approx. 17% Fe have been prepared from Fe/sub 3/(CO)/sub 12/ and the synthetic zeolites ZSM-5, mordenite and 13X by an extraction technique. The zeolites ZSM-5 and mordenite were used in the acid form, 13X in the sodium form. The catalysts were characterized by a variety of techniques including infrared spectroscopy, X-ray powder diffractometry, X-ray photoelectron spectroscopy, ion-scattering spectrometry and Mossbauer spectroscopy. All catalysts contain highly dispersed, small particle-sized ..gamma..-Fe/sub 2/O/sub 3/ with a small amount of the iron (0.6 to 1.5% Fe depending on the support) located in the pores of the support. Evaluation of the catalytic ability of some of these materials for synthesis gas conversion was conducted at 280/sup 0/C and 300/sup 0/C by using a fixed-bed continuous flow microreactor. All catalysts evaluated produce significant quantities of hydrocarbons. The distribution of hydrocarbons varies, depending upon the support used, for catalysts with similar weight percent iron. For the liquid hydrocarbons, Fe/ZSM-5 produces the highest percentage of aromatics, Fe/mordenite produces the highest percentage of olefins, and Fe/13X produces the highest percentage of saturates. The effect of support acidity and pore structure on hydrocarbon product distribution is discussed.
- Research Organization:
- Virginia Commonwealth Univ., Richmond (USA). Dept. of Chemistry
- DOE Contract Number:
- FG22-80PC30228
- OSTI ID:
- 7013465
- Report Number(s):
- DOE/PC/30228-T6; ON: DE83001584
- Resource Relation:
- Other Information: Portions of document are illegible
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
01 COAL, LIGNITE, AND PEAT
CATALYSTS
CHEMICAL PREPARATION
PERFORMANCE TESTING
SPECIFICITY
FISCHER-TROPSCH SYNTHESIS
CARBONYLS
COAL LIQUEFACTION
EXPERIMENTAL DATA
GASOLINE
INFRARED SPECTRA
IRON COMPOUNDS
MICROSTRUCTURE
MOESSBAUER EFFECT
MORDENITE
PHOTOELECTRON SPECTROSCOPY
POROSITY
SYNTHESIS GAS
X-RAY DIFFRACTION
ZEOLITES
CHEMICAL REACTIONS
COHERENT SCATTERING
CRYSTAL STRUCTURE
DATA
DIFFRACTION
ELECTRON SPECTROSCOPY
FLUIDS
FUELS
GASES
INFORMATION
INORGANIC ION EXCHANGERS
ION EXCHANGE MATERIALS
LIQUEFACTION
LIQUID FUELS
MATERIALS
MINERALS
NUMERICAL DATA
PETROLEUM PRODUCTS
SCATTERING
SILICATE MINERALS
SPECTRA
SPECTROSCOPY
SYNTHESIS
TESTING
THERMOCHEMICAL PROCESSES
TRANSITION ELEMENT COMPOUNDS
090121* - Hydrocarbon Fuels- Chemical Synthesis- (1976-1989)
010404 - Coal
Lignite
& Peat- Gasification