A study of particle settling in non-Newtonian fluids; Part 2: Rheological characterization of polymer solutions
Journal Article
·
· Journal of Energy Resources Technology; (United States)
- Univ. of Texas, Austin, TX (United States). Dept. of Petroleum Engineering
Aqueous solutions of different concentrations of three polymers: a synthetic high molecular weight polymer, partially hydrolyzed polyacrylamide (PHPA), a xanthan-type biopolymer (Xanvis), and a cellulose-type polymer (HEC) were investigated in this study. It was found that the steric arrangement of molecules or interactions between molecules can be detected by a systematically designed strain and frequency sweep measurement, and is reflected by the different relaxation times of the solutions. The degree of elasticity can be quantified by G[prime]/[vert bar]G*[vert bar] in linear viscoelastic range. The responses of the fluids to frequency sweeps are displayed in a normalized moduli versus normalized frequency pattern derived from the Maxwell model. Results show that within the tested concentration ranges, PHPA solutions are highly elastic with moderate relaxation times that are strain and concentration insensitive. Xanvis solutions are also highly elastic, but with high relaxation times that are both strain and concentration sensitive, indicating a different mechanism of elasticity compared to PHPA solutions. HEC (cellulose derivatives) are mostly viscous shear thinning fluids with weak elasticity and short relaxation times that are insensitive to strain, but sensitive to concentration.
- OSTI ID:
- 7013309
- Journal Information:
- Journal of Energy Resources Technology; (United States), Journal Name: Journal of Energy Resources Technology; (United States) Vol. 116:1; ISSN 0195-0738; ISSN JERTD2
- Country of Publication:
- United States
- Language:
- English
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02 PETROLEUM
020300* -- Petroleum-- Drilling & Production
CARBOHYDRATES
CELLULOSE
DRILLING
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FLUID MECHANICS
FLUIDS
FRACTURING
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HYDRAULIC FRACTURING
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OIL WELLS
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020300* -- Petroleum-- Drilling & Production
CARBOHYDRATES
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DRILLING
DRILLING FLUIDS
FLUID MECHANICS
FLUIDS
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OIL WELLS
ORGANIC COMPOUNDS
ORGANIC POLYMERS
PHYSICAL PROPERTIES
POLYAMIDES
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POLYSACCHARIDES
RHEOLOGY
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WELL DRILLING
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XANTHUM GUM