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Depositional environment, stratigraphy, petrology, paleogeography, and organic thermal maturation of the Desmoinesian cyclothemic Excello black shale in Oklahoma, Kansas, and Missouri

Thesis/Dissertation ·
OSTI ID:7013171
The Excello Shale is one of the most laterally continuous, thickest, and best exposed examples of a Pennsylvanian cyclothemic black shale in the Mid continent. The distribution of total organic carbon and kerogen types indicate that the Excello black shale was deposited in a epeiric highly productive sea with bottom anoxia. Thin, parallel laminations and fine particle sizes indicate quiet water conditions, while gentle undulations of strata suggest a generally flat bottom topography. The total organic carbon content averages about 10 wt% but can be as much as 17 wt%. The changes in shape and size of the phosphate nodules along the outcrop belt (spherical, bladed, elongated, and laminated) appear to be related to changes in sea water chemistry, fluctuation in organic productivity, terrestrial input and local diagenetic effects. Vitrinite reflectance (Ro% = 0.51-0.62) and elemental analysis of kerogen indicate that the outcrop samples are relatively immature with respect to hydrocarbon generation. The core samples from west-central and northwestern Oklahoma are mature (Ro% = 0.61-1.44), but most of their kerogen is recycled exhibiting multimodal distribution. This study suggests a warm and humid, climate, high rainfall, and abundant terrestrial vegetation to provide the structured kerogen which was transported into the Excello epeiric sea. A paleoclimatic and paleoceanographic model is proposed to account for the stagnant water conditions that profoundly affected the type and amount of organic matter, and the bulk sedimentation in the Excello Shale.
Research Organization:
Tulsa Univ., OK (USA)
OSTI ID:
7013171
Country of Publication:
United States
Language:
English