Aromatic nucleophilic substitution. Kinetics of reactions of pentafluorobenzene derivatives C/sub 6/F/sub 5/YR with sodium methylate and piperidine
Journal Article
·
· Kinet. Catal. (Engl. Transl.); (United States)
OSTI ID:6996094
This paper presents a kinetic study of reactions of pentafluorobenzene derivatives C/sub 6/F/sub 5/YR with sodium methylate and piperidine; also, values of omega /SUB p/ have been determined for the substituents RY in the polyfluorinated benzene ring. These values are in satisfactory agreement with values obtained for these substituents in a study of dissociation reactions of phenols and nucleophilic substitution reactions in a series of mono-substituted halobenzenes.
- Research Organization:
- Lenin Komsomol Novosibirsk State Univ.
- OSTI ID:
- 6996094
- Journal Information:
- Kinet. Catal. (Engl. Transl.); (United States), Vol. 26:3, PT. 1
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CARBOXYLIC ACID SALTS
CHEMICAL REACTION KINETICS
FLUORINATED AROMATIC HYDROCARBONS
PIPERIDINES
BENZENE
CATALYSIS
CATALYTIC EFFECTS
DIOXANE
DISSOCIATION
METHANOL
ORGANIC SULFUR COMPOUNDS
ORGANOMETALLIC COMPOUNDS
PHENOLS
SELENIUM COMPOUNDS
SODIUM COMPOUNDS
ALCOHOLS
ALKALI METAL COMPOUNDS
AMINES
AROMATICS
AZINES
HALOGENATED AROMATIC HYDROCARBONS
HETEROCYCLIC COMPOUNDS
HYDROCARBONS
HYDROXY COMPOUNDS
KINETICS
ORGANIC COMPOUNDS
ORGANIC FLUORINE COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
PYRIDINES
REACTION KINETICS
400201* - Chemical & Physicochemical Properties
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CARBOXYLIC ACID SALTS
CHEMICAL REACTION KINETICS
FLUORINATED AROMATIC HYDROCARBONS
PIPERIDINES
BENZENE
CATALYSIS
CATALYTIC EFFECTS
DIOXANE
DISSOCIATION
METHANOL
ORGANIC SULFUR COMPOUNDS
ORGANOMETALLIC COMPOUNDS
PHENOLS
SELENIUM COMPOUNDS
SODIUM COMPOUNDS
ALCOHOLS
ALKALI METAL COMPOUNDS
AMINES
AROMATICS
AZINES
HALOGENATED AROMATIC HYDROCARBONS
HETEROCYCLIC COMPOUNDS
HYDROCARBONS
HYDROXY COMPOUNDS
KINETICS
ORGANIC COMPOUNDS
ORGANIC FLUORINE COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
PYRIDINES
REACTION KINETICS
400201* - Chemical & Physicochemical Properties