Temperature dependence of the pre-exponential factors for radical thermal decomposition reactions of polyatomic molecules
Journal Article
·
· Kinet. Catal. (Engl. Transl.); (United States)
OSTI ID:6995878
Calculations were made of the pre-exponential factors A for six, radical, thermal decomposition reactions at different temperatures T. It is noted that the A factor increases rapidly in the 300-1000/sup 0/ K range (by 3-100 times) and is approximately constant at T > 1000/sup 0/ K.
- Research Organization:
- Kalinisk State Univ.
- OSTI ID:
- 6995878
- Journal Information:
- Kinet. Catal. (Engl. Transl.); (United States), Journal Name: Kinet. Catal. (Engl. Transl.); (United States) Vol. 25:6,PT. 2; ISSN KICAA
- Country of Publication:
- United States
- Language:
- English
Similar Records
A temperature dependent pre-exponential factor for kinetic equations
Temperature-dependent A factor in thermal unimolecular reactions
Thermal decomposition of benzyl iodide and of benzyl radicals in shock waves
Conference
·
Thu Nov 30 23:00:00 EST 1995
·
OSTI ID:126160
Temperature-dependent A factor in thermal unimolecular reactions
Journal Article
·
Wed Jan 10 23:00:00 EST 1979
· J. Phys. Chem.; (United States)
·
OSTI ID:6486734
Thermal decomposition of benzyl iodide and of benzyl radicals in shock waves
Journal Article
·
Thu Aug 25 00:00:00 EDT 1988
· J. Phys. Chem.; (United States)
·
OSTI ID:5992210
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKANES
ARRHENIUS EQUATION
BOND LENGTHS
CHEMICAL BONDS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
COMPUTERIZED SIMULATION
DECOMPOSITION
DIMENSIONS
DISSOCIATION ENERGY
ELECTRONIC STRUCTURE
ENERGY
ENERGY-LEVEL DENSITY
ENERGY-LEVEL TRANSITIONS
EQUATIONS
HYDROCARBONS
KINETICS
LENGTH
MOLECULES
ORGANIC COMPOUNDS
POLYATOMIC MOLECULES
PYROLYSIS
RADICALS
REACTION KINETICS
SIMULATION
TEMPERATURE DEPENDENCE
THERMOCHEMICAL PROCESSES
400201* -- Chemical & Physicochemical Properties
ALKANES
ARRHENIUS EQUATION
BOND LENGTHS
CHEMICAL BONDS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
COMPUTERIZED SIMULATION
DECOMPOSITION
DIMENSIONS
DISSOCIATION ENERGY
ELECTRONIC STRUCTURE
ENERGY
ENERGY-LEVEL DENSITY
ENERGY-LEVEL TRANSITIONS
EQUATIONS
HYDROCARBONS
KINETICS
LENGTH
MOLECULES
ORGANIC COMPOUNDS
POLYATOMIC MOLECULES
PYROLYSIS
RADICALS
REACTION KINETICS
SIMULATION
TEMPERATURE DEPENDENCE
THERMOCHEMICAL PROCESSES