Kinetics and mechanism of the oxidation of arsine by halide complexes of copper(II)

Journal Article · Fri Nov 01 00:00:00 EST 1985 · Kinet. Catal. (Engl. Transl.); (United States)

OSTI ID:6991129

Dorfman, Y A; Abdreimova, R R; Emel'yanova, V S; Kel'man, I V; Polimbetova, G S

This paper studies the kinetics of the oxidation of arsine by copper (II) halides. It is shown that within the investigated region of concentrations of the components of the system CuX/sub 2/-HX-LiX-H/sub 2/O, /SUB C/ the oxidation of AsH/sub 3/ proceeds to As(O). First order with respect to /SUB Cu/ X/sub 2/ is observed; the order with respect to C /SUB As/ H/sub 3/ is close to first. With regard to activity in the reaction with arsine, copper(II) halides are distributed in the series. CuCl /SUB 3aq/ -

• Research Organization: Institute of Organic Catalysis, Kazakh SSR Acad. of Sci., Alma-Ata
• OSTI ID: 6991129
• Journal Information: Kinet. Catal. (Engl. Transl.); (United States), Vol. 26:3, PT.1
• Country of Publication: United States
• Language: English

Related Subjects

54 ENVIRONMENTAL SCIENCES
ARSENIC COMPOUNDS
AIR POLLUTION ABATEMENT
OXIDATION
HYDROGEN COMPOUNDS
CATALYTIC EFFECTS
CHEMICAL ACTIVATION
CHEMICAL REACTION KINETICS
COPPER BROMIDES
COPPER CHLORIDES
COPPER COMPLEXES
COPPER IODIDES
EXHAUST GASES
IODINE CHLORIDES
IODOMETRY
OXIDIZERS
VALENCE
BROMIDES
BROMINE COMPOUNDS
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXES
COPPER COMPOUNDS
COPPER HALIDES
FLUIDS
GASEOUS WASTES
GASES
HALIDES
HALOGEN COMPOUNDS
IODIDES
IODINE COMPOUNDS
KINETICS
POLLUTION ABATEMENT
REACTION KINETICS
TITRATION
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
WASTES
500200* - Environment
Atmospheric- Chemicals Monitoring & Transport- (-1989)