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Experimental equations of state for calcium, strontium, and barium metals to 20 kbar from 4 to 295 K

Journal Article · · Physical Review, B: Condensed Matter; (USA)
; ;  [1]
  1. Ames Laboratory-U.S. Department of Energy, Iowa State University, Ames, Iowa 50011 (US)
Piston-displacement measurements have been used to determine the equations of state of high-purity calcium and strontium (both fcc) and barium (bcc) metals to 20 kbar from 4 to 295 K. For each metal, the results have roughly 1% accuracy for the {ital P}=0 bulk modulus at 295 K and for the total volume change with pressure. The results also give the change with temperature of both the {ital P}=0 volume and the isothermal bulk modulus for these metals. While the bulk moduli for calcium and strontium are dependent only on the volume, those for barium show a significant temperature dependence with decreasing volume. Specifically, the bulk modulus for barium at 10 kbar is roughly 3% smaller at 295 K than would be predicted from the 0-K value at the same volume. Differences between the pressure-volume relations for bare samples and for those which were jacketed with indium metal are not understood.
DOE Contract Number:
W-7405-ENG-82
OSTI ID:
6978745
Journal Information:
Physical Review, B: Condensed Matter; (USA), Journal Name: Physical Review, B: Condensed Matter; (USA) Vol. 41:6; ISSN 0163-1829; ISSN PRBMD
Country of Publication:
United States
Language:
English