Multistage process for converting oxygenates to distillate hydrocarbons with interstage ethene recovery
This patent describes a continuous multi-stage catalytic system for converting oxygenated feedstock to liquid hydrocarbons. It comprises: primary stage catalytic dehydration means containing catalyst for converting oxygenate to light olefinic vapor and normally liquid C{sub 5}{sup +} hydrocarbons; interstage separation means for recovering water and hydrocarbons from the primary stage effluent stream; first fractionation means for recovering ethene from the primary stage olefinic vapor including a sorption tower operatively connected to selectively sorb C{sub 3}{sup +} hydrocarbons from the olefinic vapor in a liquid sorption stream; means for pressurizing and heating the liquid sorption stream containing C{sub 3}{sup +} sorbate; secondary stage catalytic oligomerization reactor means containing medium pore shape selective zeolite oligomerization catalyst for converting olefinic hydrocarbons in the sorption stream to liquid hydrocarbons comprising a major amount of distillate; second fractionation means for separating secondary stage effluent into a light hydrocarbon stream rich in C{sub 3}-C{sub 4} aliphatic hydrocarbons a C{sub 5}{sup +} gasoline stream and distillate range stream; and means for recycling at least a portion of the C{sub 5}{sup +} gasoline stream to the first fractionation means.
- Assignee:
- Mobil Oil Corp., New York, NY
- Patent Number(s):
- US 4898717; A
- Application Number:
- PPN: US 6-689638A
- OSTI ID:
- 6975990
- Resource Relation:
- Patent File Date: 7 Jan 1985
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
ALKENES
CATALYTIC CRACKING
GASOLINE
PRODUCTION
PETROLEUM
CATALYSTS
DEHYDRATION
EVAPORATION
FRACTIONATION
PETROLEUM DISTILLATES
ZEOLITES
CHEMICAL REACTIONS
CRACKING
DECOMPOSITION
DISTILLATES
ENERGY SOURCES
FOSSIL FUELS
FUELS
HYDROCARBONS
INORGANIC ION EXCHANGERS
ION EXCHANGE MATERIALS
LIQUID FUELS
MATERIALS
MINERALS
ORGANIC COMPOUNDS
PETROLEUM FRACTIONS
PETROLEUM PRODUCTS
PHASE TRANSFORMATIONS
PYROLYSIS
SEPARATION PROCESSES
THERMOCHEMICAL PROCESSES
020400* - Petroleum- Processing