Mesoxalaldehyde acetals

Journal Article · Tue Nov 10 00:00:00 EST 1987 · J. Org. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:6974916

Gordeeva, G N; Kalashnikov, S M; Popov, Yu N; Kruglov, E A; Imashev, U B

The treatment of methylglyoxal acetals by alkyl nitrites in the presence of the corresponding aliphatic alcohols and hydrochloric acid leads to the formation of linear mesoxalaldehyde acetals, whose structure was established by NMR spectroscopy and mass spectrometry. The major pathways for the decomposition of these molecules upon electron impact were established.

• Research Organization: Ufa Petroleum Institute (USSR)
• OSTI ID: 6974916
• Journal Information: J. Org. Chem. USSR (Engl. Transl.); (United States), Vol. 23:6; Other Information: Translated from Zh. Org. Khim.; 23: No. 6, 1158-1163(Jun 1987)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
74 ATOMIC AND MOLECULAR PHYSICS
ACETALS
IONIZATION
MASS SPECTRA
NMR SPECTRA
ALDEHYDES
CHEMICAL REACTION KINETICS
CHEMICAL SHIFT
COUPLING CONSTANTS
DISSOCIATION
ELECTRON BEAMS
ELECTRON-MOLECULE COLLISIONS
J-J COUPLING
MOLECULAR IONS
MOLECULAR STRUCTURE
STRUCTURAL CHEMICAL ANALYSIS
BEAMS
CHARGED PARTICLES
COLLISIONS
COUPLING
ELECTRON COLLISIONS
ETHERS
INTERMEDIATE COUPLING
IONS
KINETICS
LEPTON BEAMS
MOLECULE COLLISIONS
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
PARTICLE BEAMS
REACTION KINETICS
SPECTRA
400201* - Chemical & Physicochemical Properties
640302 - Atomic
Molecular & Chemical Physics- Atomic & Molecular Properties & Theory
640304 - Atomic
Molecular & Chemical Physics- Collision Phenomena