Kinetics and mechanism of the reaction of styrene with diazoacetic ester in the presence of cobalt phthalocyanine

Journal Article · Sun Sep 20 00:00:00 EDT 1987 · J. Org. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:6974777

Pazynina, G V; Kaliya, O L; Luk'yanets, E A; Bolesov, I G

The kinetics of the catalytic reaction of styrene with diazoacetic ester in the presence of cobalt tetra-4-tert-butylphthalocyanine were investigated. The proposed reaction scheme includes the formation of a complex between the diazoacetic ester and the catalyst, the decomposition of which leads to the production of carbenoid particle. The latter then reacts with the olefin to form cyclopropane derivatives.

• Research Organization: Scientific-Research Institute of Organic Intermediates and Dyes, Moscow (USSR)
• OSTI ID: 6974777
• Journal Information: J. Org. Chem. USSR (Engl. Transl.); (United States), Vol. 23:4; Other Information: Translated from Zh. Org. Khim.; 23: No. 4, 813-817(Apr 1987)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ACETIC ACID ESTERS
CATALYSIS
COBALT COMPLEXES
CATALYTIC EFFECTS
CYCLOALKANES
CHEMICAL REACTION YIELD
DIAZO COMPOUNDS
PHTHALOCYANINES
STYRENE
CATALYSTS
CHEMICAL REACTION KINETICS
KINETIC EQUATIONS
PROPANE
ALKANES
ALKYLATED AROMATICS
AROMATICS
CARBOXYLIC ACID ESTERS
COMPLEXES
DYES
EQUATIONS
ESTERS
HETEROCYCLIC COMPOUNDS
HYDROCARBONS
KINETICS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
REACTION KINETICS
TRANSITION ELEMENT COMPLEXES
YIELDS
400201* - Chemical & Physicochemical Properties