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Title: Reactivity of zirconium basic sulfate in the reactions with carbonate, oxalate, and phosphate reagents

Abstract

The reactivity of zirconium basic sulfate is determined by the possibility of replacement of oxo- and hydroxo-ligands and decreases with increasing temperature of its precipitation. The interaction of the less reactive zirconium basic sulfate with carbonate and oxalate reagents occurs at 25/sup 0/C without any change in basicity and that with phosphate reagents occurs with a decrease in it, up to the formation of a monophosphate with basicity about 20%. In the interaction of the more reactive zirconium basic sulfate, obtained without heating, oxo- and hydroxo groups can be entirely replaced by acido-ligands with the formation of unhydrolyzed compounds.

Authors:
; ; ;
Publication Date:
OSTI Identifier:
6974588
Alternate Identifier(s):
OSTI ID: 6974588
Resource Type:
Journal Article
Journal Name:
J. Appl. Chem. USSR (Engl. Transl.); (United States)
Additional Journal Information:
Journal Volume: 60:3; Other Information: Translated from Zh. Prikl. Khim.; 60: No. 3, 481-485(Mar 1987)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ZIRCONIUM SULFATES; ACTIVATION ENERGY; CHEMICAL REACTION KINETICS; PRECIPITATION; PRODUCTION; BASES; COMPLEXOMETRY; DISSOLUTION; OXALATES; PH VALUE; POTENTIOMETRY; ZIRCONIUM CARBONATES; ZIRCONIUM COMPLEXES; ZIRCONIUM PHOSPHATES; CARBON COMPOUNDS; CARBONATES; CARBOXYLIC ACID SALTS; COMPLEXES; ENERGY; KINETICS; OXYGEN COMPOUNDS; PHOSPHATES; PHOSPHORUS COMPOUNDS; REACTION KINETICS; SEPARATION PROCESSES; SULFATES; SULFUR COMPOUNDS; TITRATION; TRANSITION ELEMENT COMPLEXES; TRANSITION ELEMENT COMPOUNDS; ZIRCONIUM COMPOUNDS 400201* -- Chemical & Physicochemical Properties

Citation Formats

Nekhamkin, L.G., Kondrashova, I.A., Kerina, V.R., and Kolpachkova, N.M. Reactivity of zirconium basic sulfate in the reactions with carbonate, oxalate, and phosphate reagents. United States: N. p., 1987. Web.
Nekhamkin, L.G., Kondrashova, I.A., Kerina, V.R., & Kolpachkova, N.M. Reactivity of zirconium basic sulfate in the reactions with carbonate, oxalate, and phosphate reagents. United States.
Nekhamkin, L.G., Kondrashova, I.A., Kerina, V.R., and Kolpachkova, N.M. Thu . "Reactivity of zirconium basic sulfate in the reactions with carbonate, oxalate, and phosphate reagents". United States.
@article{osti_6974588,
title = {Reactivity of zirconium basic sulfate in the reactions with carbonate, oxalate, and phosphate reagents},
author = {Nekhamkin, L.G. and Kondrashova, I.A. and Kerina, V.R. and Kolpachkova, N.M.},
abstractNote = {The reactivity of zirconium basic sulfate is determined by the possibility of replacement of oxo- and hydroxo-ligands and decreases with increasing temperature of its precipitation. The interaction of the less reactive zirconium basic sulfate with carbonate and oxalate reagents occurs at 25/sup 0/C without any change in basicity and that with phosphate reagents occurs with a decrease in it, up to the formation of a monophosphate with basicity about 20%. In the interaction of the more reactive zirconium basic sulfate, obtained without heating, oxo- and hydroxo groups can be entirely replaced by acido-ligands with the formation of unhydrolyzed compounds.},
doi = {},
journal = {J. Appl. Chem. USSR (Engl. Transl.); (United States)},
number = ,
volume = 60:3,
place = {United States},
year = {1987},
month = {8}
}