Glass structure and optical nonlinearities in thallium(I) tellurium (IV) oxide glasses
- ESA CNRS, Limoges (France). Lab. de Materiaux Ceramiques et Traitements de Surface; and others
The relationships between structure and nonlinear optical response at 1.5 {micro}m in thallium(I) tellurite glasses are investigated. Usually in tellurite glasses, the introduction of a modifier ion changes the basic structural TeO{sub 4} disphenoid entity progressively into a TeO{sub 3} trigonal bipyramid via an intermediate TeO{sub 3+1} polyhedron. This evolution leads to a decrease of the nonlinear refractive index n{sub 2}. Nevertheless, if a modifier ion such as Tl{sup +} also has an ns{sup 2} lone electron pair, n{sub 2} increases although the same structural evolution is observed around the tellurium atoms. This result is related to the hyperpolarizability of the thallium oxygen entities, which has been evidenced by the structural study of both thallium(I) tellurite crystals and glasses of the same compositions. With this solid state chemistry approach, the highest nonlinear refractive index measured at 1.5 {micro}m (n{sub 2} = 9.10{sup {minus}19} m{sup 2}/W) and reported in oxide glasses has been obtained.
- OSTI ID:
- 696668
- Journal Information:
- Journal of Solid State Chemistry, Vol. 146, Issue 2; Other Information: PBD: Sep 1999
- Country of Publication:
- United States
- Language:
- English
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