Insertion of SnCl/sub 2/ into an Os-Os bond of Os/sub 3/(CO)/sub 11/(. mu. -CH/sub 2/) to give the planar cluster Os/sub 3/SnCl/sub 2/(CO)/sub 11/(. mu. -CH/sub 2/) with a pentacoordinate tin atom
Journal Article
·
· Inorg. Chem.; (United States)
Studies have revealed that the planar cluster compounds, Os/sub 3/SnCl/sub 2/(CO)/sub 11/(..mu..-CH/sub 2/), is formed by the insertion of SnCl/sub 2/ into the Os-Os bond when SnCl/sub 2/ reacts with Os/sub 3/(..mu..-Ch/sub 2/)(CO). The cluster compound was characterized spectroscopically and defined by x-ray diffraction studies. 13 references, 1 figure, 1 table.
- Research Organization:
- Pennsylvania State Univ., University Park
- OSTI ID:
- 6962446
- Journal Information:
- Inorg. Chem.; (United States), Journal Name: Inorg. Chem.; (United States) Vol. 25:17; ISSN INOCA
- Country of Publication:
- United States
- Language:
- English
Similar Records
Clusters containing carbene ligands. 3. The transformations of a (dimethylamino)methyl ligand in a triosmium cluster. The synthesis and structural characterizations of Os/sub 3/(CO)/sub 10/(. mu. -eta/sup 2/-H/sub 2/CNMe/sub 2/)(. mu. -H), Os/sub 3/(CO)/sub 9/(. mu. /sub 3/-eta/sup 2/-C(H)NMe/sub 2/)(. mu. -H)/sub 2/, and Os/sub 3/(CO)/sub 10/(. mu. -CNMe/sub 2/)(. mu. -H)
Clusters containing carbene ligands. 9. Reaction of MeC triple bond CNMe sub 2 with Os sub 3 (CO) sub 10 (. mu. -H) sub 2
Trinuclear osmium clusters as models for intermediates in carbon monoxide reduction chemistry. 1. Stepwise reduction of CO to a. mu. -CH/sub 2/ ligand on an Os/sub 3/ cluster face
Journal Article
·
Thu Mar 31 23:00:00 EST 1988
· Organometallics; (United States)
·
OSTI ID:7005133
Clusters containing carbene ligands. 9. Reaction of MeC triple bond CNMe sub 2 with Os sub 3 (CO) sub 10 (. mu. -H) sub 2
Journal Article
·
Tue May 01 00:00:00 EDT 1990
· Organometallics; (USA)
·
OSTI ID:6519029
Trinuclear osmium clusters as models for intermediates in carbon monoxide reduction chemistry. 1. Stepwise reduction of CO to a. mu. -CH/sub 2/ ligand on an Os/sub 3/ cluster face
Journal Article
·
Wed May 02 00:00:00 EDT 1984
· J. Am. Chem. Soc.; (United States)
·
OSTI ID:6805196
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKENES
CARBONYLS
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXES
DATA
EXPERIMENTAL DATA
HALIDES
HALOGEN COMPOUNDS
HYDROCARBONS
INFORMATION
NUMERICAL DATA
ORGANIC COMPOUNDS
OSMIUM COMPLEXES
SYNTHESIS
TIN CHLORIDES
TIN COMPOUNDS
TIN HALIDES
TRANSITION ELEMENT COMPLEXES
400201* -- Chemical & Physicochemical Properties
ALKENES
CARBONYLS
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXES
DATA
EXPERIMENTAL DATA
HALIDES
HALOGEN COMPOUNDS
HYDROCARBONS
INFORMATION
NUMERICAL DATA
ORGANIC COMPOUNDS
OSMIUM COMPLEXES
SYNTHESIS
TIN CHLORIDES
TIN COMPOUNDS
TIN HALIDES
TRANSITION ELEMENT COMPLEXES