Electrochemical generation of phosphorus-containing ion-radicals with simultaneous recording of EPR signal and electrochemical characteristics
Journal Article
·
· Dokl. Phys. Chem. (Engl. Transl.); (United States)
OSTI ID:6961228
The electrochemical generation of ion-radicals, especially under controlled conditions, widens the possibilities of a thorough theoretical analysis of the electronic structure of the compounds and of the rules governing the consecutive chemical reactions. In this work, the authors used a specially constructed three-electrode spiral vacuum cell to study at various temperatures certain unsaturated organophosphorus compounds containing two phosphorus atoms in the molecule. The possibility was envisaged of applying galvanometric pulses to the working electrode, containing the EPR spectrometer resonator, while controlling the potential, time, and intensity of the EPR signal, as well as poentiodynamic and potentiostatic pulses. The EPR spectra were recorded on a Bruker-Physik spectrometer. HFS constants are given for the ion-radicals studied.
- OSTI ID:
- 6961228
- Journal Information:
- Dokl. Phys. Chem. (Engl. Transl.); (United States), Journal Name: Dokl. Phys. Chem. (Engl. Transl.); (United States) Vol. 294:4-6; ISSN DKPCA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400400* -- Electrochemistry
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ANIONS
CARBON 13
CARBON ISOTOPES
CHARGED PARTICLES
CHEMISTRY
ELECTROCHEMISTRY
ELECTRODES
ELECTROLYSIS
ELECTRON SPIN RESONANCE
ELECTRONIC STRUCTURE
EPR SPECTROMETERS
EVEN-ODD NUCLEI
HYPERFINE STRUCTURE
IONS
ISOTOPES
LIGHT NUCLEI
LINE WIDTHS
LYSIS
MAGNETIC RESONANCE
MEASURING INSTRUMENTS
NUCLEI
ORGANIC COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
POTENTIOMETRY
RADICALS
RESONANCE
SPECTRA
SPECTROMETERS
STABLE ISOTOPES
STRUCTURAL CHEMICAL ANALYSIS
TITRATION
VALENCE
400400* -- Electrochemistry
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ANIONS
CARBON 13
CARBON ISOTOPES
CHARGED PARTICLES
CHEMISTRY
ELECTROCHEMISTRY
ELECTRODES
ELECTROLYSIS
ELECTRON SPIN RESONANCE
ELECTRONIC STRUCTURE
EPR SPECTROMETERS
EVEN-ODD NUCLEI
HYPERFINE STRUCTURE
IONS
ISOTOPES
LIGHT NUCLEI
LINE WIDTHS
LYSIS
MAGNETIC RESONANCE
MEASURING INSTRUMENTS
NUCLEI
ORGANIC COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
POTENTIOMETRY
RADICALS
RESONANCE
SPECTRA
SPECTROMETERS
STABLE ISOTOPES
STRUCTURAL CHEMICAL ANALYSIS
TITRATION
VALENCE