Novel macrocyclic carriers for proton-coupled liquid membrane transport

Technical Report · Wed Jul 01 04:00:00 EDT 1992

DOI:https://doi.org/10.2172/6957516· OSTI ID:6957516

Lamb, J D; Bradshaw, J S; Izatt, R M

A number of new macrocyclic ligands was prepared for transport studies. The cryptands were prpepared (18-40% yield) by a new metal carbonate-catalyzed one-step method from 1 mole oligoethyleneoxy diamine and 2 moles diahlide derivative of oligoethylene glycol. Bis-crown ethers were also isolated in 17-30% yields. Cage compounds were also prepared; they interact with various metal ions and protons. Back extraction and dual module hollow fiber membrane separation experiments were used to study the cation selectivity of new ligands, including crown thioethers. An isothermal flow calorimeter is being constructed for studies of macrocycle-cation reactions. 3 figs, 2 tabs.

• Research Organization: Brigham Young Univ., Provo, UT (United States). Dept. of Chemistry
• Sponsoring Organization: DOE; USDOE, Washington, DC (United States)
• DOE Contract Number: FG02-86ER13463
• OSTI ID: 6957516
• Report Number(s): DOE/ER/13463-9; ON: DE93003160
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400105 -- Separation Procedures
400201* -- Chemical & Physicochemical Properties
ALCOHOLS
CALORIMETERS
CATIONS
CHARGED PARTICLES
DOCUMENT TYPES
GLYCOLS
HYDROXY COMPOUNDS
IONS
LIGANDS
MEASURING INSTRUMENTS
MEMBRANE TRANSPORT
MERCURY IONS
ORGANIC COMPOUNDS
ORGANIC POLYMERS
ORGANIC SULFUR COMPOUNDS
POLYETHYLENE GLYCOLS
POLYMERS
PROGRESS REPORT