Structural effects of hydrostatic pressure in Sr[sub 1[minus][ital x]][ital M][sub [ital x]]CuO[sub 2] ([ital M]=La,Ca) and Sr[sub 4]Cu[sub 6]O[sub 10]
- Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439 (United States)
- Materials Science and Engineering Department, University of Illinois, Urbana, Illinois 61801 (United States)
- The Institute of Scientific and Industrial Research, Osaka University, 8-1 Mihogaoka, Ibaraki, Osaka 567 (Japan)
Pressure effects on the tetragonal infinite-layer structure were studied in superconducting Sr[sub 0.9]La[sub 0.1]CuO[sub 2] (electron-doped) and Sr[sub 0.7]Ca[sub 0.3]CuO[sub 2] (hole-doped) samples, and in an insulating nonsuperconducting Sr[sub 0.14]Ca[sub 0.86]CuO[sub 2] sample, using time-of-flight neutron powder diffraction. Neutron-diffraction measurements, with the sample at room temperature, were performed at several hydrostatic pressures up to [approx]0.6 GPa on each of the three samples, using a helium-gas pressure cell. The measured compressibilities, which are similar for the three samples, show a large anisotropy, and are in a good agreement with first-principles calculations performed for undoped Sr[sub 0.7]Ca[sub 0.3]CuO[sub 2]. Atomic size effects of the [ital A] atom in [ital A]CuO[sub 2] on the crystal lattice are discussed and are compared with the pressure effects. A relation is found between the in-plane compressibilities among [ital n]-layer ([ital n]=1,2,3 . . .,[infinity]) structures of high-[ital T][sub [ital c]] superconductors.
- Research Organization:
- Argonne National Laboratory (ANL), Argonne, IL
- DOE Contract Number:
- W-31109-ENG-38
- OSTI ID:
- 6955472
- Journal Information:
- Physical Review, B: Condensed Matter; (United States), Journal Name: Physical Review, B: Condensed Matter; (United States) Vol. 50:17; ISSN PRBMDO; ISSN 0163-1829
- Country of Publication:
- United States
- Language:
- English
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Structure of superconducting Sr[sub 0. 9]La[sub 0. 1]CuO[sub 2] ([ital T][sub [ital c]]=42 K) from neutron powder diffraction
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Related Subjects
360602* -- Other Materials-- Structure & Phase Studies
ALKALINE EARTH METAL COMPOUNDS
AMBIENT TEMPERATURE
CALCIUM COMPOUNDS
CALCIUM OXIDES
CHALCOGENIDES
COHERENT SCATTERING
COMPRESSIBILITY
COPPER COMPOUNDS
COPPER OXIDES
CRYSTAL STRUCTURE
DIELECTRIC MATERIALS
DIFFRACTION
HIGH-TC SUPERCONDUCTORS
LANTHANUM COMPOUNDS
LANTHANUM OXIDES
MATERIALS
MECHANICAL PROPERTIES
NEUTRON DIFFRACTION
OXIDES
OXYGEN COMPOUNDS
PRESSURE DEPENDENCE
RARE EARTH COMPOUNDS
SCATTERING
STRONTIUM COMPOUNDS
STRONTIUM OXIDES
SUPERCONDUCTORS
TIME-OF-FLIGHT METHOD
TRANSITION ELEMENT COMPOUNDS
VERY HIGH PRESSURE