The solvation of the ground and transition states in the reaction of ortho-palladized acetanilide with styrene in organic solvents

Journal Article · Tue Jul 01 00:00:00 EDT 1986 · Kinet. Catal. (Engl. Transl.); (United States)

OSTI ID:6952769

Sakodynskaya, I K; Neverov, A A; Ryabov, A D; Yatsimirskii, A K

The rate of the reaction of di-mu-chlorobis(acetanilidato-2C, 0) dipalladium(II) with styrene leading to 2-acetaminostilbene was found in 11 organic solvents. In all media, the reaction has second-order kinetics. The free energy, enthalpy and entropy of activation were determined in each solvent. The data for the solubility of the starting Pd(II) complex were used to determine the free energy for the transfer of the ground state of this reaction from a standard solvent (heptane) to the other solvents. The analogous transfer functions were calculated for the transition state. The correlation of the transfer functions of the starting and transition states of this reaction with empirical solvent parameters was examined.

• Research Organization: M.V. Lomonsov Moscow State Univ
• OSTI ID: 6952769
• Journal Information: Kinet. Catal. (Engl. Transl.); (United States), Vol. 27:1,PT. 1
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
AMIDES
CHEMICAL REACTION KINETICS
PALLADIUM COMPLEXES
CATALYTIC EFFECTS
STYRENE
ACTIVATION ENERGY
FREE ENTHALPY
GROUND STATES
ORGANIC CHLORINE COMPOUNDS
ORGANIC SOLVENTS
ORGANOMETALLIC COMPOUNDS
SOLUBILITY
SOLVATION
SOLVENT PROPERTIES
SPECTROPHOTOMETRY
ALKYLATED AROMATICS
AROMATICS
COMPLEXES
ENERGY
ENERGY LEVELS
HYDROCARBONS
KINETICS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PHYSICAL PROPERTIES
REACTION KINETICS
SOLVENTS
THERMODYNAMIC PROPERTIES
TRANSITION ELEMENT COMPLEXES
400201* - Chemical & Physicochemical Properties