Charge exchange at molecular-orbital pseudocrossings as an important mechanism for nonkinetic-electron emission in slow-multicharged-ion (v

Journal Article · Thu Sep 01 00:00:00 EDT 1988 · Phys. Rev. A; (United States)

DOI:https://doi.org/10.1103/PhysRevA.38.2294· OSTI ID:6950708

Snowdon, K J; Havener, C C; Meyer, F W; Overbury, S H; Zehner, D M; Heiland, W

Kinetic energy distributions of electrons emitted in the interaction of slow (10q-keV) multicharged ions (N,O,Ne,Ar) with metal surfaces (Cu,Au) are presented. We observe secondary-electron emission, quasielastic-scattering processes, and, superimposed upon this, one-center Auger decay of both projectile and target vacancies. Two classes of target Auger-decay features are observed. Long-lived target vacancies decay, leading to discrete Auger line features, similar to those arising from electron-impact excitation. Short-lived target vacancies appear to decay in the field of the projectile, leading to broadened Auger line features. Observation of the decay of target vacancies, and their correlation with the presence of particular projectile vacancies, shows that a measurable fraction of projectile vacancies survive until small-impact-parameter collisions with surface or subsurface atoms. The data imply that projectile neutralization proceeds via two channels, viz., capture of valence-band electrons to projectile excited states, followed by one-center Auger decay, and at pseudocrossings of molecular orbitals correlating with discrete inner-shell levels of the target and projectile.

• Research Organization: Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831
• OSTI ID: 6950708
• Journal Information: Phys. Rev. A; (United States), Vol. 38:5
• Country of Publication: United States
• Language: English

Related Subjects

75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
GOLD
AUGER EFFECT
ENERGY SPECTRA
ION COLLISIONS
SECONDARY EMISSION
RARE GASES
ANGULAR DISTRIBUTION
BEAM NEUTRALIZATION
COPPER
MONOCRYSTALS
MULTICHARGED IONS
NITROGEN
OXYGEN
SURFACES
CHARGED PARTICLES
COLLISIONS
CRYSTALS
DISTRIBUTION
ELEMENTS
EMISSION
FLUIDS
GASES
IONS
METALS
NONMETALS
SPECTRA
TRANSITION ELEMENTS
656003* - Condensed Matter Physics- Interactions between Beams & Condensed Matter- (1987-)