Route of autooxidation of organic compounds through a metal ion and bromide catalysis

Journal Article · Tue Dec 31 23:00:00 EST 1985 · Pet. Chem. USSR (Engl. Transl.); (United States)

DOI:https://doi.org/10.1016/0031-6458(86)90016-X· OSTI ID:6950340

Zakharov, I V; Geletii, Y V

Liquid-phase oxidation of organic compounds is normally an autocatalytic process and proceeds by a branched-chain mechanism through intermediate formation of peroxides. Decomposition of peroxides into free radicals ensures branching of the chain and consequently autoacceleration of the reaction. This is a study of such an oxidation using a cobalt-bromide catalysts. The reaction and its kinetics are thoroughly investigated, and a mechanism is reported.

• Research Organization: Moscow Physicotechnical Institute (USSR)
• OSTI ID: 6950340
• Journal Information: Pet. Chem. USSR (Engl. Transl.); (United States), Journal Name: Pet. Chem. USSR (Engl. Transl.); (United States) Vol. 26:4; ISSN PECHA
• Country of Publication: United States
• Language: English

Related Subjects

02 PETROLEUM
023000 -- Petroleum-- Properties & Composition
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
BROMIDES
BROMINE COMPOUNDS
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
COBALT COMPOUNDS
DATA
EXPERIMENTAL DATA
FLUIDS
HALIDES
HALOGEN COMPOUNDS
INFORMATION
KINETICS
LIQUIDS
NUMERICAL DATA
ORGANIC COMPOUNDS
OXIDATION
REACTION KINETICS
TRANSITION ELEMENT COMPOUNDS