Formation of ozone in the reaction between the ozonide radical ion, O/sub 3//sup -/, and the carbonate radical ion, CO/sub 3//sup -/, in aqueous alkaline solutions. [Electron beams]
Journal Article
·
· J. Phys. Chem.; (United States)
Ozone forms in aqueous alkaline solutions by a reaction between the O/sub 3//sup -/ and CO/sub 3//sup -/ radical ions. This reaction has been demonstrated under conditions favorable for the generation of suitable concentrations of these ions by a high-pressure pulse radiolysis technique. The reaction is O/sub 3//sup -/ + CO/sub 3//sup -/ ..-->.. O/sub 3/ + CO/sub 3//sup 2 -/. Its rate constant k/sub (O/sub 3//sup -/+CO/sub 3//sup -/)/ of (6 +- 2) x 10/sup 7/ dm/sup 3/ mol/sup -1/ s/sup -1/ has been determined by computer simulation of the reactions involved.
- Research Organization:
- Risoe National Lab., Roskilde, Denmark
- OSTI ID:
- 6937932
- Journal Information:
- J. Phys. Chem.; (United States), Journal Name: J. Phys. Chem.; (United States) Vol. 86:11; ISSN JPCHA
- Country of Publication:
- United States
- Language:
- English
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· J. Phys. Chem.; (United States)
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Journal Article
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Related Subjects
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400600* -- Radiation Chemistry
ALKALI METAL COMPOUNDS
AQUEOUS SOLUTIONS
BEAMS
CARBON COMPOUNDS
CARBONATES
CHEMICAL RADIATION EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHEMISTRY
DECOMPOSITION
DISPERSIONS
ELECTRON BEAMS
HYDROGEN COMPOUNDS
IRRADIATION
KINETICS
LEPTON BEAMS
MIXTURES
OXYGEN COMPOUNDS
OZONE
PARTICLE BEAMS
PH VALUE
PULSED IRRADIATION
RADIATION CHEMISTRY
RADIATION EFFECTS
RADICALS
RADIOLYSIS
REACTION KINETICS
SODIUM CARBONATES
SODIUM COMPOUNDS
SOLUTIONS
SYNTHESIS
WATER
400600* -- Radiation Chemistry
ALKALI METAL COMPOUNDS
AQUEOUS SOLUTIONS
BEAMS
CARBON COMPOUNDS
CARBONATES
CHEMICAL RADIATION EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHEMISTRY
DECOMPOSITION
DISPERSIONS
ELECTRON BEAMS
HYDROGEN COMPOUNDS
IRRADIATION
KINETICS
LEPTON BEAMS
MIXTURES
OXYGEN COMPOUNDS
OZONE
PARTICLE BEAMS
PH VALUE
PULSED IRRADIATION
RADIATION CHEMISTRY
RADIATION EFFECTS
RADICALS
RADIOLYSIS
REACTION KINETICS
SODIUM CARBONATES
SODIUM COMPOUNDS
SOLUTIONS
SYNTHESIS
WATER