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Solvent extraction of oil-sand components for determination of trace elements by neutron activation analysis

Journal Article · · Anal. Chem.; (United States)
DOI:https://doi.org/10.1021/ac00252a021· OSTI ID:6928630

Instrumental neutron activation analysis was used to measure the concentrations of 30 elements in Athabasca oil sands and oil-sand components. The oil sands were separated into solid residue, bitumen, and fines by Soxhlet extraction with toluene-bitumen extract. The mineral content of the extracted bitumen was dependent on the treatment of the oil sand prior to extraction. The geochemically important and organically associated trace element contents of the bitumen (and asphaltenes) were determined by subtracting the mineral contributions from the total measured concentrations. The method allows analysis of the bitumen without the necessity of ultracentrifugation or membrane filtration, which might remove geochemically important components of the bitumen. The method permits classification of trace elements into organic and inorganic combinations.

Research Organization:
Washington State Univ., Pullman
OSTI ID:
6928630
Journal Information:
Anal. Chem.; (United States), Journal Name: Anal. Chem.; (United States) Vol. 55:1; ISSN ANCHA
Country of Publication:
United States
Language:
English

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